Cations |
(positive
ions) |
IONS How do I remember the
charges? Group 1
metals always have a charge of +1. Group 1 metals like sodium lose 1 electron to gain a full octet (a full
outer shell of 8 electrons). Group 2
metals always have a charge of +2. Group 2 metals like magnesium lose 2 electrons to gain a full octet. Group 7
halogens always have a charge of -1. Group 1 metals like sodium lose 1 electron to gain a full octet. Oxygen in
ions always has a charge of -2. Whether the oxygen atom is an ion on its own (oxide ion), or part of a
molecular ion like hydroxide, oxygen always has two more electrons than it
does protons, and so a charge of -2. Nitrogen in
ions always has a charge of -3. Carbon and
silicon in ions always have a charge of +4. What is an ion? An atom or
molecule that has lost or gained electrons. Atoms that are ions are called simple ions. Atoms that are molecules are called molecular ions. Atoms and molecules normally have no overall electric charge. There’s no charge on an atom because the number of positive
protons in the nucleus is equal to the number of negative electrons whizzing
around the nucleus. The positive
and negative charges cancel each other out. If an atom or molecule loses one electron, there is one
positively-charged proton that does not have a negatively-charged electron to
cancel out its charge. So the
overall charge on the atom or molecule is +1. If an atom or molecule gains one electron, there is one
negatively-charged electron that does not have a positively-charged proton to
cancel out its charge. So the
overall charge on the atom or molecule is -1. The same rule applies if more than one electron is gained or lost. If two negative electrons are lost,
the amount of negative charge on the atom or molecule decreases, so the
resultant (overall) charge becomes more positive. It’s better to say the resultant charge gets more positive or
more negative than to talk about the overall charge increasing or
decreasing. When considering
electric charges, increasing doesn’t always mean getting more positive. Note: when I have written things
like “oxygen always has a charge of -2” this isn’t
absolutely always true in real life, but it is true for GCSE. Just remember that sometimes they
don’t tell you the whole story so that you don’t have to be
examined on the tricky reasons for the exceptions to the rules. If you’re annoyed that
you’re told to believe things that aren’t true then firstly well
done, that’s a good attitude.
But secondly, be happy because it’s one more thing that you
don’t have to remember for the exam. If you really want to know, in some unusual
compounds, oxygen can be O22- (peroxide ion) or O2-
(superoxide ion). If you have any
other questions, I will find out the answer for you. Email me at chem@benjamin-mills.com. |
H+ |
Hydrogen |
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Li+ |
Lithium |
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Na+ |
Sodium |
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K+ |
Potassium |
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Ag+ |
Silver |
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NH4+ |
Ammonium |
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Mg2+ |
Magnesium |
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Ca2+ |
Calcium |
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Be2+ |
Beryllium |
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Cu2+ |
Copper(II) |
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Zn2+ |
Zinc |
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Pb2+ |
Lead |
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Fe2+ |
Iron(II) |
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Fe3+ |
Iron(III) |
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Al3+ |
Aluminium |
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Anions |
(negative
ions) |
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OH- |
Hydroxide |
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F - |
Fluoride |
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Cl - |
Chloride |
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Br - |
Bromide |
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I - |
Iodide |
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NO3 - |
Nitrate |
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O2- |
Oxide |
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S2- |
Sulphide |
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CO3 2- |
Carbonate |
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SO4 2- |
Sulphate* |
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SiO3 2- |
Silicate |
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A-level |
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ClO- |
Hypochlorite / chlorate(I) |
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ClO2- |
Chlorite / chlorate(III) |
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ClO3- |
Chlorate / chlorate(V) |
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ClO4- |
Perchlorate / chlorate(VII) |
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CN- |
Cyanide |
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Co2+ |
Cobalt(II) |
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Co3+ |
Cobalt(III) |
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Cr2O72- |
Dichromate / dichromate(VI) |
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Cr3+ |
Chromium(III) |
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CrO4- |
Chromate / chromate(VII) |
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Cs+ |
Caesium |
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Cu+ |
Copper(I) |
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H3O+ |
Oxonium / hydroxonium / hydronium |
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HCO3- |
Hydrogencarbonate |
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Mn2+ |
Manganese(II) |
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Mn3+ |
Manganese(III) |
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MnO4- |
Permanganate / manganate(VII) |
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MnO42- |
Manganate(VI) |
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Ni2+ |
Nickel(II) |
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NO2- |
Nitrite / nitrate(III) |
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NO2+ |
Nitronium |
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PO43- |
Phosphate |
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Rb+ |
Rubidium |
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S2O32- |
Thiosulphate |
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S2O82- |
Persulphate / peroxodisulphate |
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Sc3+ |
Scandium |
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Sn2+ |
Tin(II) / Stannous |
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Sn4+ |
Tin(IV) / Stannic |
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SO32- |
Sulphite / sulphate(IV) |
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Sr2+ |
Strontium |
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Ti3+ |
Titanium(III) |
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