Cations

(positive ions)

IONS

 

 

How do I remember the charges?

Group 1 metals always have a charge of +1.

Group 1 metals like sodium lose 1 electron to gain a full octet (a full outer shell of 8 electrons).

 

Group 2 metals always have a charge of +2.

Group 2 metals like magnesium lose 2 electrons to gain a full octet.

 

Group 7 halogens always have a charge of -1.

Group 1 metals like sodium lose 1 electron to gain a full octet.

 

Oxygen in ions always has a charge of -2.

Whether the oxygen atom is an ion on its own (oxide ion), or part of a molecular ion like hydroxide, oxygen always has two more electrons than it does protons, and so a charge of -2.

 

Nitrogen in ions always has a charge of -3.

Carbon and silicon in ions always have a charge of +4.

 

What is an ion?

An atom or molecule that has lost or gained electrons.

 

Atoms that are ions are called simple ions.

Atoms that are molecules are called molecular ions.

 

Atoms and molecules normally have no overall electric charge.

There’s no charge on an atom because the number of positive protons in the nucleus is equal to the number of negative electrons whizzing around the nucleus.  The positive and negative charges cancel each other out.

 

If an atom or molecule loses one electron, there is one positively-charged proton that does not have a negatively-charged electron to cancel out its charge.  So the overall charge on the atom or molecule is +1.

 

If an atom or molecule gains one electron, there is one negatively-charged electron that does not have a positively-charged proton to cancel out its charge.  So the overall charge on the atom or molecule is -1.

 

The same rule applies if more than one electron is gained or lost.  If two negative electrons are lost, the amount of negative charge on the atom or molecule decreases, so the resultant (overall) charge becomes more positive.

 

It’s better to say the resultant charge gets more positive or more negative than to talk about the overall charge increasing or decreasing.  When considering electric charges, increasing doesn’t always mean getting more positive.

 

Note: when I have written things like “oxygen always has a charge of -2” this isn’t absolutely always true in real life, but it is true for GCSE.  Just remember that sometimes they don’t tell you the whole story so that you don’t have to be examined on the tricky reasons for the exceptions to the rules.

 

If you’re annoyed that you’re told to believe things that aren’t true then firstly well done, that’s a good attitude.  But secondly, be happy because it’s one more thing that you don’t have to remember for the exam.

 

If you really want to know, in some unusual compounds, oxygen can be O22- (peroxide ion) or O2- (superoxide ion).  If you have any other questions, I will find out the answer for you.  Email me at chem@benjamin-mills.com.

H+

Hydrogen

Li+

Lithium

Na+

Sodium

K+

Potassium

Ag+

Silver

NH4+

Ammonium

 

 

Mg2+

Magnesium

Ca2+

Calcium

Be2+

Beryllium

Cu2+

Copper(II)

Zn2+

Zinc

Pb2+

Lead

Fe2+

Iron(II)

 

 

Fe3+

Iron(III)

Al3+

Aluminium

 

 

Anions

(negative ions)

OH-

Hydroxide

F -

Fluoride

Cl -

Chloride

Br -

Bromide

I -

Iodide

NO3 -

Nitrate

 

 

O2-

Oxide

S2-

Sulphide

CO3 2-

Carbonate

SO4 2-

Sulphate*

SiO3 2-

Silicate

 

 

A-level

 

ClO-

Hypochlorite / chlorate(I)

ClO2-

Chlorite / chlorate(III)

ClO3-

Chlorate / chlorate(V)

ClO4-

Perchlorate / chlorate(VII)

CN-

Cyanide

Co2+

Cobalt(II)

Co3+

Cobalt(III)

Cr2O72-

Dichromate / dichromate(VI)

Cr3+

Chromium(III)

CrO4-

Chromate / chromate(VII)

Cs+

Caesium

Cu+

Copper(I)

H3O+

Oxonium / hydroxonium / hydronium

HCO3-

Hydrogencarbonate

Mn2+

Manganese(II)

Mn3+

Manganese(III)

MnO4-

Permanganate / manganate(VII)

MnO42-

Manganate(VI)

Ni2+

Nickel(II)

NO2-

Nitrite / nitrate(III)

NO2+

Nitronium

PO43-

Phosphate

Rb+

Rubidium

S2O32-

Thiosulphate

S2O82-

Persulphate / peroxodisulphate

Sc3+

Scandium

Sn2+

Tin(II) / Stannous

Sn4+

Tin(IV) / Stannic

SO32-

Sulphite / sulphate(IV)

Sr2+

Strontium

Ti3+

Titanium(III)

 

 

 

 

 

 

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